• Vibrational and electronic circular dichroism of Δ-TRISPHAT [tris(tetrachlorobenzenediolato)phosphate(V)] anion
    D. Bas, T. Bürgi, J. Lacour, J. Vachon and J. Weber
    Chirality, 17 (S1) (2005), p143-148
    DOI:10.1002/chir.20131 | unige:3628 | Abstract | Article PDF
 
Herein is reported an experimental and theoretical study of the circular dichroism properties of TRISPHAT (1) anion. ECD analysis of the [tetramethylammonium][Δ-1] salt confirms the absolute configuration assignment obtained through X-ray crystallographic analysis of the parent cinchonidium salt. The structure, infrared, and vibrational circular dichroism (VCD) spectra derived from density functional theory (DFT) calculations are compared with experimental data.

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